S&T | New non-toxic organic photocatalyst can efficiently capture CO2 and convert to methane

Indian Scientists have designed a cost-effective metal-free catalyst to convert carbon dioxide to methane by absorption of visible light. Ongoing research is making a significant effort to reduce CO₂ into value-added products, methane (CH₄) could be one of the value-added products with significant uses as the cleanest burning fossil fuel and can directly be used in fuel cells as a hydrogen carrier.  It is also the main component of natural gas and has the potential to replace coal for electricity generation and furnishing flexible supply to reinforce intermittent renewable generators.

There are several ways in which CO₂ can be reduced, including photochemical, electrochemical, photoelectrochemical, photothermal, and so on. The photochemical process utilizes solar light as a renewable energy source.

There are some key requirements of a photo-catalyst to convert CO₂ into value-added products, which rely upon the light-harvesting property, charge carrier (electron-hole pair) separation proficiency, and presence of proper electronically aligned conduction band. Thus, it is a challenge to reduce CO₂ to CH₄ selectively and efficiently. Only a handful of catalysts are able to reduce CH₄ selectively and efficiently, and most of the catalyst contains metal counterparts which are toxic and expensive.

In order to overcome this challenge, a team of Scientists from Jawaharlal Nehru Centre for Advanced Scientific Research, an autonomous institute of the Department of Science & Technology, Government of India, have designed a metal-free porous organic polymer in such a way that it will be able to absorb visible light and catalyze the CO₂ reduction reaction as well.

They have prepared a donor (tris-4-ethynylphenylamine)-acceptor (phenanthaquinone) assembly via C-C coupling to form a robust and thermally stable conjugated microporous organic polymer which was utilized as a heterogeneous catalyst. The keto group present in phenanthraquinone moiety acted as a catalytic site in contrast with other conventional metal-based catalysts where the metal counterpart carries out the CO₂ reduction reaction (CO₂RR). During the catalysis process, first, the chemical called the conjugated microporous polymer (CMP) could uptake CO₂ onto its surface due to its high CO₂ intake capability at room temperature, converting it into methane as a value-added product. The synergistic push-pull effect between the electron-rich donor and electron-deficient acceptor facilitated efficient electron-hole separation, enhancing electron transfer kinetics and assisting in efficient catalysis. This work has been accepted for publication in the Journal of the American Chemical Society. The utilization of a cost-effective, metal-free system with a high production rate of CH₄ can lead to a new strategic way to assemble carbon capture and reduction based on efficient porous heterogeneous catalysts.

Schematic showing CO₂ capture and visible-light-driven conversion of CO₂ to solar fuel CH₄  using a metal-free redox-active conjugated microporous polymer.

Prof. Tapas. K. Maji     Dr. Soumitra Barman    Dr. Ashish Singh     Faruk Ahamed Rahimi

Publication link: 10.1021/jacs.1c07916.

For more details, Prof. Tapas K. Maji may be contacted at [email protected].